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6.0) FIRE and SMOKE: (page
1 of 6)
6.1) Mitigation Objective:
The objective when performing mitigation services after a fire
or smoke loss is to prevent the post environmental conditions
of
smoke,
soot,
hydrocarbons,
nitrogen,
sulfur,
corrosive
gases,
moisture
and standing water from producing
irresolvable damages.
The mitigation process should include the
envelope of
the building, its structural members and
substratum, as well as
its electrical, mechanical, and
telecommunication systems when
affected. While contents of value should also be
mitigated.
The mitigation of any specific item or group
of items should not exceed the value of the item being
mitigated as described in
Section 6.13.b.
6.1.a) Restoration Objective:
The
objective when
performing
restoration services after fire, smoke or water losses is to
return the damaged property to its
pre-existing condition.
Dependent on the post-damages; cleaning,
restoration, or reconstruction could be required, while all
three disciplines could be required within a single loss.
The reconstruction or replacement of building components is
based on like kind and quality as described in
Section 6.1.b.
Contractors should not include betterments
or upgrades within their scope of work, unless the insurance
policy contains betterment or up-grade provisions. While betterment or upgrades
when added by the policyholder, and extend
business interruption (BI) or
additional living expense
(ALE) up and beyond the scope of work covered by the insurance
policy, should be brought to the attention of the adjuster.
6.1.b) Like Kind and Quality:
Insurance companies will pay the
replacement value of building component and content items based
on like kind and quality. The term, “like
kind and quality”
is based on the ever-changing styles, etc. of building
components and content items. To contractors like kind and
quality means, a discontinued component or item should be replaced with a
component or item having the same likeness, quality and value. (ref.
1.6)
6.2) Work Authorization:
Before the mitigation process begins, contractors
should have an
emergency response work authorization signed by the property owner(s)
and/or policyholders before work commences. The emergency
response work authorization should not include the disciplines
of restoration or reconstruction. The
work authorization for restoration and/or reconstruction
should be signed separately of the emergency response work
authorization.
6.3) Documentation: When
performing mitigation or emergency services, contractors should
document all disciplines performed.
6.4) Intentionally Left Blank:
6.5)
Policy Coverage:
Before the mitigation or restoration process
begins, policy type and coverage should be confirmed with
the adjuster and/or insurance agent or broker.
6.6) Safety and Health:
All personnel shall put safety and health first. Upon arrival
to the loss site, the designated crew chief should make a safety
and health inspection. This should include atmospheric
conditions as well as structural hazards. (ref.
3.0)
Copies of
MSDS
sheets for all chemicals and materials should be available at the loss site at
all times.
6.6.a) Children's Belongings and Objects:
Children's toys, furnishings, bedding, personal
objects, etc. should be cleaned and disinfected after a fire and
smoke loss. While it, is preferable that all toys, personal
objects and bedding be disposed of when used by infants of 3
years or less?
When a fire source contains
PVC products, children’s belongings and objects should be
tested for
lead contaminates and remediated or discarded when lead
deposits are found.
(ref.
6.16.b)
6.7) Time is of the Essence:
Surfaces react quickly to smoke, soot, and gases, resulting in
contractors to be racing against the clock. This is especially
true when a corrosive atmospheric condition exists.
The following surfaces and time frames are
examples of how crucial timing, as well as an adequate (in
stock) supply of varying cleaning chemicals is to contractors:
- Impact: Metal and steel surfaces can be affected by
hydrogen chloride (HCl) gases on impact.
- Minutes: Plastics, small appliances, marble, etc. can discolor.
- Hours:
Grout, fiberglass, plumbing fixtures (chrome), brass, coated
steel, appliances, hard wood and upholstered furniture can
discolor.
- Days: Painted walls and ceilings can discolor, plated metals pit
and
rust, vinyl floors, clothing and upholstery can permanently
stain.
- Weeks: Carpets can discolor, plated metals corrode, glass,
crystal and
china can etch and pit.
All of which could be
permanent or non-cost effective by means of restoration.
6.8)
Smoke and Soot: Smoke
can be gases, vapor or solid and is generally brown in color,
which can change to white/gray when mixed with the water actions
of firefighters. Black smoke is generally from burning
plastics, which can also change colors when mixed with water.
Soot or PIC's (particles
of incomplete combustion) are the by-products of a fire that
did not burn efficiently, and are produced when a fire was not
hot enough or did not have enough oxygen to fully burn. Soot or
PIC's can be organic or inorganic matter and based on the fuel
source, a combination of organic and inorganic soot could be
deposited throughout.
Smoke could contain gaseous by-products such as;
carbon monoxide
and
hydrogen cyanide (which are toxic and deadly), acrolein
(which is an irritant and a potential toxin) and hydrogen
chloride (which is toxic irritant and highly corrosive).
PIC's and smoke are deposited throughout a structure through
turbulence and
wavelengths. Hot smoke and soot travel towards
cool air and matter, which is caused when heat increases the
internal energy of an object causing disorder in an objects’
atoms and molecules.
Organic materials are carbons and produce nitrogen (NO2), while
inorganic materials produce sulfur (SO2) when burned. Both of
which are
hydrocarbons,
and hydrocarbons can be
carcinogenic.
Smoke and soot can form on sides, tops and undersides of content
items such as; chairs, tables, appliances, equipment, machinery,
etc.
When structural components within a room have signs of smoke and
soot deposits, be it gaseous vapors or solids, content items are
generally affected.
6.8.a) Gases: Oxidation
at a loss site can vary from room to room and within a room, possibly due to the cooling of gases as they travel throughout
a structure, for hot gaseous particles move faster than colder
gaseous particles. Gaseous particles move at the speed of sound
in all directions, as gaseous particles become hotter their
speed increases, causing moving gaseous particles to crash into
billions of other particles each second. This is due to the way
gases such as carbon dioxide, nitrogen, oxygen and hydrogen
react to temperatures.
When matter is decomposed, gaseous chemicals are produced and
their behavior is
kinetic energy. As the temperature of the gaseous particles
increase, their impacting rate are intensified and could affect
surfaces. This is especially true of metals and hydrogen
chloride gases when combined; which can create a soluble
stimulus or influential reaction of the metals molecules.
Gas molecules are so intensive that the volume of gas particles
within a 22.4 liter container at 0º C can contain 602 billion
trillion particles (602,000,000,000,000,000,000,000). While
these gas particles can expand by their same fraction at each
degree that the temperature rises.
6.9) Smoke and Soot Categorizing:
The post conditions from a fire, smoke and soot loss can be
categorized into three grades; those being light, medium and
heavy:
Light conditions: Light-soiling deposits of smoke and
soot can be neutralized with basic cleaning detergents and
skills.
Medium conditions: Moderate-soiling deposits of smoke and
soot could require a more aggressive chemical and moderate
skills to neutralize.
Heavy conditions: Heavy smoke and soot deposits could
require extensive cleaning methods, as well as refinishing or
replacement.
Fire and smoke losses can produce all three grades of soiling
within a single structure due to the following listed variables:
source (fuel), pattern, temperature, oxygen, pressure, water
use, combustion, moisture and time. Dependent on the fuel
source, temperature and time, some light and medium surfaces
could require sealing and painting after the surfaces are
mitigated and cleaned.
6.10) Loss Site Specifics:
After the structure has been determined safe, the
following specifics should be determined:
- Time fire started and was extinguished
- Extinguishing method
- Was water used? If water was used, number of gallons used?
- Origin room
- Fuel source of fire
- Extent of damages
- Temperature, humidity and dew point
- Surface types on a room per room basis
- Severity of damages, heavy, medium or light
- Available power and light
- Cost Vs value
The aforementioned information would aid the mitigation process
when determining what can or cannot be mitigated and/or
restored, and help when performing a business impact analysis as
outlined in
Section 6.13.
Temperature ºC
|
Kw |
|
0
10
20
25
60
|
0.114 *
0.295
*
0.676
*
0.100 *
9.550 * |
Value of Kw
at Various Temperatures
K = Equilibrium Constant,
w
= Water
Source: Cotton-Lynch, Chemistry an
Investigative Approach
Table 6-A
6.10.a) Extinguishing Methods: The
extinguishing method used to control and put out a fire can have
adverse affects, and should be classified as
incidental damages.
The following extinguishing methods are commonly used to control
and put out fires:
- Water
- Foam
- Gases
- Halogen
- Dry chemicals
Water, foam and gases can be mixed by firefighters when
extinguishing a fire, while dry chemicals, halogen and
carbon dioxide are used when water and foams can cause
danger to life, such as electrical fires.
Certain dry chemicals and
halogen systems contain
chlorides
(Cl)
which are corrosive to metals and electrical equipment, while
foams can entrap hydrogen chloride (HCl) gases when produced
during a fire.
The extinguishing agent used, amount of the agent used, and
where used should be obtained from the fire department.
This information
is very useful when evaluating a loss site as to what cleaning
agents should or should not be used. The fire class could be
helpful when determining what extinguishing methods were used.
6.10.b) Fire Classes: The
United States and Great Britain have developed fire
classification to determine what extinguishing agents should or
should not be used:
U.S. Classes:
- Class A: wood, paper, cloth, and some plastics
- Class B: flammable liquids, gases and grease
- Class C: electrical fires
- Class D: combustible metals
British Classes:
- Class A: Carbon compounds that form glowing
embers
- Class B: Liquid or liquefiable solids
- B1: Water miscible
- B2: Non-miscible with water
- Class C: Flammable gases or vapors
- Class D: Metal fires
- Class E: Electrical fires
Fire and
Smoke: Page:
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Extracted from the Loss
Recovery Guide with Standards (LRGS)
© Copyright 1998-2008
William Yobe
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6.10.c) Time Fire Started and was Extinguished: The
time the fire started and was extinguished can be used to
determine the severity of surface conditions. The time frames
found in
Section 6.7 is pertinent to metal, porcelain and fine
wood surfaces when the fuel source contains plastic and the fire
was extinguished using water.
6.10.d) Water Usage: Firefighter
actions can deposit 100's to 1000's of gallons of water when
extinguishing a fire. The amount of water used to extinguish
the fire, the atmospheric temperature, humidity and dew point of
the structure would help determine the amount of drying
equipment, and the time frame needed to dry the structure and
its contents.
When
the origin room and adjoining rooms contains extensive amounts of moisture, it/they
should
be isolated from the balance of the structure. The isolating of
high moisture rooms from the balance of the structure could
delay corrosive reactions and secondary damages (mold) within
the balance of the structure.
Before the restorative drying process begins, an assessment of
the loss site should be performed using the
p1m.com Critical Recovery Flow Chart.
6.10.e) Moisture: Moisture
is a natural occurring by-product of combustion. The combustion
of both organic and inorganic materials such as; gypsum
wallboard, plaster, wood, nylon, etc. when decomposed will
produce moisture through vaporization when the solid transforms
into a gaseous vapor.
Fires extinguished with carbon dioxide and foam a/k/a dry
chemicals, can retain and seal in moisture for a considerable
time. (ref.
6.10.a)
Regardless of the fuel source or extinguishing method,
temperature, humidity and dew point readings should be taken and
restorative drying should start when humidity conditions are at
41% or higher or when there is standing water.
6.11) Fire Source and
Types of Materials Ignited: The fuel source or types of
materials that burned can be used to determine the types of soot
particles to be removed or neutralized,.
Soot residue could be organic, synthetic, or a combination of
both. The soot composition could be oily, dry, greasy or
acidic, or a combination of all four.
Hazardous building materials such as lead, asbestos, and
polychlorinated biphenyl (PCB's) when decomposed produce
toxic gases that could linger for days after a fire.
When PCB's are a known fuel source and PCB soot is deposited
throughout a structure, the structure and its contents would
require an extensive decontamination. PCB is a listed
hazard with the
ATSDR (ref.
3.21).
When building components or content items made from or
containing
polyvinyl chloride (PVC) are decomposed, the
impacting of hydrogen chloride (HCl) gases on metal surfaces
could be present, requiring inspection, testing and confirmation
before neutralizing of metal surfaces.
The method, chemical agents and equipment required for
mitigation is best determined after the fuel source, types of
materials ignited and decomposed are identified, and the
physical make-up of the surface being mitigated is determined.
6.12) Temperature, Humidity and Dew-Point:
Temperature, humidity and dew point readings
should be taken and recorded at the loss sites at the start of
the project and on a daily basis until the project is completed.
6.13) Business Impact Analysis (BIA): A
business impact analysis
identifying the effect a loss has on an organization should be required as part of the
organizations contingency plan. The specific information
outlined in
Section 6.10
could aid risk managers when performing an impact
analysis, and should be helpful when determining:
- Financial and non-financial costs
- Establishing time window of recovery
- Preliminary assessment of materials and equipment
6.13.a) Fuel Source: Fuel
sources could be organic or inorganic. Fuels such as; wood,
coal, oil, lime and foods produce the by-products
carbon
dioxide, while nylon, polyester, and plastics produce the
by-product
sulfur dioxide.
Hydrogen chloride (HCl) can be produced from both organic and
inorganic matter, while polyvinyl chloride (PVC) produces HCl
when decomposed.
When the fuel source is being determined, surface types,
reaction time, condition and location should be used to
prioritize the mitigation of the surface.
6.13.b) Damage Vs Value:
Before mitigation services begin, the values of mitigation,
restoration and reconstruction should be pre-determined.
The value to mitigate and restore may exceed the value to
replace when business interruption (BI) insurance costs are
factored. However, the excess costs to mitigate and restore, may
or may not be the responsibility of the insurer.
Cost to perform board-up procedures may exceed
value if replacement materials such as windows, doors, roofing,
siding, etc. are not presently available, or when safety, health, or vandalism is an issue.
6.13.c) Temporary Power and Light: Loss
sites where the electrical power is turned-off or disabled
and natural illumination does not meet the minimum requirements
set forth by
OSHA, should be illuminated by a
temporary means. Generator or temporary service mast is
acceptable temporary power sources, while the back feeding of an
electrical system within a structure should only be performed
by, or under the direct supervision of a licensed or
certified electrician.
Secondary damages of
corrosion to wiring, conduits, boxes, panels, etc., could be
delayed or put in a state of dormancy when energized.
6.13.d) Secondary Damage: Fire
and smoke losses could create secondary damage such as; mold and
corrosion when not mitigated in a timely manner or proper
fashion.
6.13.e) Mold: Mold
(fungi) growth after a fire loss is generally secondary damage caused by
extinguishing water that produces excessive humidity, while
stagnant air and high temperatures stimulate mold growth.
6.13.f) Origin Room: The mitigation of building
components or content items within the origin room should
not commence until the
cause and origin (C&O) evaluation process is completed, and
access is granted by the person in charge of the C&O process.
(ref.1.10)
6.13.g) Corrosion (Rust) Damage: Rust
caused by carbonic acids and hydrochloric acid would be a
red/orange colored rust and have a powder like scale. Corrosion
(rust) under usual environments is called an
electrochemical
phenomenon and is the reaction of moisture and oxygen to metal
surfaces, and defined as a
cathodic reaction. The use of
inhibitor
pigments or paints greatly enhance corrosion
resistance which restrict the flow of galvanic currents and
prevent cathodic reactions.
Corrosion (rust)
caused by
hydrogen chloride gases,
hydrochloric acid and heat
from a fire or smoke loss produce an accelerated rate of free
energy known as electrokinetics.
Electrokinetics release
positive and negative ions that cause electromotive forces
(EMF's) as found in the
electromotive or
electrochemical
series. These electrical forces or
electron actions when forced
from the atom produce EMF’s that can be measured in milligauss (mG).
EMF’s cause metal molecules to align as shown in
Figure 6-13-A
and 6-13-B.

Domain Aligned
Molecules in Iron
Source: Bell Labs, Division of Lucent
Technologies &
The Illustrated Science and Invention Encyclopedia
Figure 6-13-A

Right Angle and Domain Align of an Alnico Alloy
Source: Bell Labs, Division of Lucent Technologies &
The Illustrated Science and Invention Encyclopedia
Figure 6-13-B
Figures 6-13-A and 6-13-B are the ©
1999 Bell Labs,
Lucent Technologies, Inc. Reprinted with
permission of
Lucent Technologies, Inc., Murray Hill, NJ
EMF's caused from hydrochloric acid, although
still producing measurable actions, could decrease considerably
when air and surface temperatures drop to or below freezing as
shown in
Table 6-A.
The free energy produced on metal surfaces during corrosion
is an anodic reaction and the corrosion area is the cathodic
area. The following formulas are anodic reactions:The potential current range where EMF’s are produced is shown
in
Figure 6-13-C below

Potential-Current Diagram
Source: The Making Shaping and Treating of Steel
© 1999 American Iron and
Steel Engineers Foundation
Pittsburgh, PA -
AISE Steel Foundation
Figure 6-13-C
Listed below are electromotive
forces caused from hydrogen chloride, hydrochloric acid heat,
varying chemicals, etc. resulting in pre-mature corrosion:
-
Thermal action:
Produces EMF's when a temperature in a conductor (metal) varies in magnitude
-
Chemical action: Certain combinations of chemicals will generate EMF's
-
Contact action: Two different materials when brought together will produce EMF's
-
Crystal action: Certain crystals such as salt have the property to produce EMF's, while heat can further increase crystal EMF's
Thermionic emission: The
heating of a metal to a high enough temperature, so the free electrons in the metal breaks through the surface of the metal.
Secondary emission: The bombarding of a metal surface with electrons or ions (electrically charged particles of matter) of sufficiently high kinetic
energy.
Electromagnetic induction:
When sufficient energy is produced, the magnetic field of the affected matter will continually change and produce EMF's,
Acids, both hydrochloric and carbonic cause charged bodies to be
passed from the metal to the chemical increasing a metals’ free
energy, resulting in the driving force behind the accelerated
oxidation rates,
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